Removal of Arsenic from Simulated Groundwater Using GAC‐Ca in Batch Reactor: Kinetics and Equilibrium Studies     

Prasenjit Mondal  Bikash Mohanty  Chandrajit Balo Majumder 《洁净——土壤、空气、水》2012,40(5):506-514

This paper deals with kinetics and equilibrium studies on the adsorption of arsenic species from simulated groundwater containing arsenic (As(III)/As(V), 1:1), Fe, and Mn in concentrations of 0.188, 2.8, and 0.6 mg/L, respectively, by Ca²⁺ impregnated granular activated charcoal (GAC‐Ca). Effects of agitation period and initial arsenic concentration on the removal of arsenic species have also been described. Although, most of the arsenic species are adsorbed within 10 h of agitation, equilibrium reaches after ～24 h. Amongst various kinetic models investigated, the pseudo second order model is more adequate to explain the adsorption kinetics and film diffusion is found to be the rate controlling step for the adsorption of arsenic species on GAC‐Ca. Freundlich isotherm is adequate to explain the adsorption equilibrium. However, empirical polynomial isotherm gives more accurate prediction on equilibrium specific uptakes of arsenic species. Maximum specific uptake (q_max) for the adsorption of As(T) as obtained from Langmuir isotherm is 135 µg/g.  相似文献   

Chromite and PGE deposits of mesoarchaean ultramafic-mafic suites within the greenstone belts of the Singhbhum craton,India: Implications for mantle heterogeneity and tectonic setting     

Sisir K. Mondal 《Journal of the Geological Society of India》2009,73(1):36-51

The Archaean cratonic nuclei of the continents are important as they contain the most significant evidences for the evolution of Earth e.g. the greenstone sequences. In the Indian Shield, one of the important cratons is the Singhbhum craton, where nearly 95% of the Indian chromite deposits and only PGE deposits are located which are hosted within Mesoarchaean ultramafic-mafic rock sequences. The ultramafic units occur as sill like intrusions within the Iron Ore Group (IOG) greenstone belts and often associated with gabbroic intrusions. In the Nuasahi and Sukinda mining districts of these occurrences, detailed petrological, geochemical and isotopic studies have been carried out in the last decades. Petrological and geochemical studies indicate a supra-subduction zone (SSZ) tectonic settings in Archaean for the origin of these ultramafic-mafic sequences. The Os isotopic and platinum group element (PGE) geochemical studies of chromites from the two mining districts indicate presence of a subchondritic source mantle domain beneath and within the Singhbhum craton similar to the Zimbabwean craton of southern African continent. The Os model age calculation indicates melt extraction from a subcontinental lithospheric mantle (SCLM) before 3.7 Ga which is similar to the other ancient cratons. As a whole the study supports the premise that India was part of the African continent in pre-Gondwana times and even in early Archaean and suggest possible amalgamation and building up of a supercontinent during late Archaean. However, in comparison with other occurrences, the Singhbhum craton of the Indian Shield and the Zimbabwean craton in southern Africa are characterized by the presence of subchondritic lithospheric mantle domains within the SCLM, which were developed prior to 3.7 Ga.  相似文献   

Palaeomagnetic and rock magnetic study of charnockites from Tamil Nadu,India, and the ‘Ur’ protocontinent in Early Palaeoproterozoic times     

S. Mondal  J.D.A. Piper  L. Hunt  G. Bandyopadhyay  S. Basu Mallik 《Journal of Asian Earth Sciences》2009,34(4):493-506

Palaeomagnetic and magnetomineralogical results are reported from charnockites in basement terrane at the eastern sector of the WSW–ENE granulite belt of South India. Magnetite is the dominant ferromagnet identified by rock magnetic and optical study; it is present in several phases including large homogeneous titanomagnetites and disseminated magnetite in microfractures linked to growth stages ranging from primary charnockite formation to uplift decompression and exhumation within the interval ～2500–2100 Ma. Several components of magnetization are resolved by thermal demagnetization and summarized by four pole positions; in the northern (Pallavaram) sector these are P1 (33°N, 99°E, dp/dm = 8/9°) and P2 (79°N, 170°E, dp/dm = 3/6°), and in the southern (Vandallur) sector they are V1 (23°N, 116°E, dp/dm = 8/9°) and V2 (26°S, 136°E, dp/dm = 5/10°). These magnetizations are linked to uplift cooling of the basement and unblocking temperature spectra suggest acquisition sequences P1 → P2 and V1 → V2 in each case implying movement of the shield from higher to lower palaeolatitudes sometime between 2500 and 2100 Ma. Palaeomagnetic poles from the cratonic nuclei of Africa, Australia and India all identify motion from higher to lower palaeolatitudes in Early Palaeoproterozoic times, and this is dated ～2400 and ～2200 Ma in the former two shields. The corresponding apparent polar wander (APW) segments match the magnetization record within the charnockite basement terranes of southern India to yield a preliminary reconstruction of the ‘Ur’ protocontinent, the oldest surviving continental protolith with origins prior to 3000 Ma. Although subject to later relative movements these nuclei seem to have remained in proximity until the Mesozoic break-up of Gondwana.  相似文献   

Aquifer characteristics and its modeling around an industrial complex,Tuticorin, Tamil Nadu,India: A case study   总被引：3，自引：0，他引：3  

N. C. Mondal  V. S. Singh  R. Rangarajan 《Journal of Earth System Science》2009,118(3):231-244

Anthropogenic pollution of shallow groundwater resources due to industrial activities is becoming a cause of concern in the east coastal belt of the state of Tamil Nadu, India. Integrated hydrogeological, geophysical and tracer studies were carried out in the coastal region encompassing an industrial complex. The objective has been to gain knowledge of aquifer characteristics, ascertaining groundwater movement and its flow direction, which would in turn reveal the possibility of contamination of groundwater regime and its better management. The results of multi-parameters and model study indicate that the velocity of groundwater flow ranges from 0.013 m/d to 0.22m/d in and around the industrial complex in upstream western part of the catchment and 0.026 m/d to 0.054m/d in the downstream eastern part, near the coast. These parameters are vital for the development of groundwater management scheme.  相似文献   

Forest cover change prediction using hybrid methodology of geoinformatics and Markov chain model: A case study on sub-Himalayan town Gangtok,India     

Anirban Mukhopadhyay  Arun Mondal  Sandip Mukherjee  Dipam Khatua  Subhajit Ghosh  Debasish Mitra  Tuhin Ghosh 《Journal of Earth System Science》2014,123(6):1349-1360

In the Himalayan states of India, with increasing population and activities, large areas of forested land are being converted into other land-use features. There is a definite cause and effect relationship between changing practice for development and changes in land use. So, an estimation of land use dynamics and a futuristic trend pattern is essential. A combination of geospatial and statistical techniques were applied to assess the present and future land use/land cover scenario of Gangtok, the subHimalayan capital of Sikkim. Multi-temporal satellite imageries of the Landsat series were used to map the changes in land use of Gangtok from 1990 to 2010. Only three major land use classes (built-up area and bare land, step cultivated area, and forest) were considered as the most dynamic land use practices of Gangtok. The conventional supervised classification, and spectral indices-based thresholding using NDVI (Normalized Difference Vegetation Index) and SAVI (Soil Adjusted Vegetation Index) were applied along with the accuracy assessments. Markov modelling was applied for prediction of land use/land cover change and was validated. SAVI provides the most accurate estimate, i.e., the difference between predicted and actual data is minimal. Finally, a combination of Markov modelling and SAVI was used to predict the probable land-use scenario in Gangtok in 2020 AD, which indicted that more forest areas will be converted for step cultivation by the year 2020.  相似文献   

Fractal study of seismicity in order to characterize the various tectonic blocks of North-east Himalaya,India   总被引：1，自引：1，他引：0  

Roy  P. N. S.  Chowdhury  Suparna  Sarkar  Partha  Mondal  Saroj Kumar 《Natural Hazards》2014,72(1):5-22

Three major projects initiated by the European Commission within its 7th Framework Programme that have studied the weather phenomena and their projections to the future in relation to their impacts and implications to the European transport systems have recently been concluded. All of the transport modes were covered, as well as all of the critical phenomena present within the European area. The three projects (that ran from 2009 and 2012) are as follows: (1) EWENT (Extreme Weather impacts on European Networks of Transport—www.ewent.vtt.fi); (2) ECCONET (Effects of climate change on the inland waterway networks—www.ecconet.eu); (3) WEATHER (Weather Extremes: Assessment of Impacts on Transport and Hazards for European Regions—www.weather-project.eu). In this Foreward to the Special Issue on “Vulnerability of Transportation to Extreme Weather and Climate Change,” the key results of the above three projects are addressed concisely, offering the reader a broader view of their findings; since some of these are enveloped in the research papers hosted in this volume, they will not be covered in detail. However, the rich output of these projects in the form of “Project Deliverables” and “Reports” is also an important source of information on the findings and results from these three projects which are publicly available on the projects’ Web sites. The purpose of this Foreward is to bring to the attention of the interested reader these sources and overview briefly some of the projects’ outcomes. Also, a short comparative discussion on selected findings is made, outlining agreements and disagreements between the projects.  相似文献   

A study of mylonites from parts of the Salem-Attur shear zone (Tamil Nadu) and its tectonic implications     

T. K. Biswal  V. Thirukumaran  Kamleshwar Ratre  Krishanu Bandyapadhaya  K. Sundaralingam  Amit Kumar Mondal 《Journal of the Geological Society of India》2010,75(1):128-136

The E-W running Salem-Attur shear zone demarcates the tectonic boundary between Archaean Dharwar Craton in the north and Proterozoic Southern granulite terrane in the south. This study reveals that the shear zone is a low angle thrust. The thrust zone is around 10 m thick and it merges with the main shear zone along the strike. The thrust is developed on charnockite near Odyarpatti, which is retrograded into schists. Further, it is marked by gently dipping mylonitic foliation and subhorizontal lineation. The S-C fabric, mantled porphyroclasts and intragranular faults indicate northeasterly slip along the thrust. Recumbent shear folds SF₁ are developed within the thrust zone. The thrust has been folded by late stage F₂ fold which has brought variation in the orientation of the mylonitic foliation from subhorizontal to vertical attitude; the mylonitic lineations have been rotated to subvertical orientation also. Additionally, the F₂ crenulations and shear cleavages and intersection lineations are superimposed on the mylonitic fabric. Thrusting along the Salem-Attur shear zone is probably the cause for upliftment of the charnockites to the upper crust. Post-upliftment stage has witnessed brittle deformation in the form of development of shear fractures in NNE-SSW and E-W directions. Pseudotachylites are emplaced along these fractures.  相似文献   

Geophysical Characterization of the Salna Sinking Zone, Garhwal Himalaya, India     

Rambhatla G. Sastry  Suman K. Mondal 《Surveys in Geophysics》2013,34(1):89-119

Infrastructure and communication facilities are repeatedly affected by ground deformation in Gharwal Himalaya, India; for effective remediation measures, a thorough understanding of the real reasons for these movements is needed. In this regard, we undertook an integrated geophysical and geotechnical study of the Salna sinking zone close to the Main Central Thrust in Garhwal Himalaya. Our geophysical data include eight combined electrical resistivity tomography (ERT) and induced polarization imaging (IPI) profiles spanning 144–600 m, with 3–10 m electrode separation in the Wenner–Schlumberger configuration, and five micro-gravity profiles with 10–30 m station spacing covering the study region. The ERT sections clearly outline the heterogeneity in the subsurface lithology. Further, the ERT, IPI, and shaliness (shaleyness) sections infer the absence of clayey horizons and slip surfaces at depth. However, the Bouguer gravity analysis has revealed the existence of several faults in the subsurface, much beyond the reach of the majority of ERT sections. These inferred vertical to subvertical faults run parallel to the existing major lineaments and tectonic elements of the study region. The crisscross network of inferred faults has divided the entire study region into several blocks in the subsurface. Our studies stress that the sinking of the Salna village area is presently taking place along these inferred vertical to subvertical faults. The Chamoli earthquake in March 1999 probably triggered seismically induced ground movements in this region. The absence of few gravity-inferred faults in shallow ERT sections may hint at blind faults, which could serve as future source(s) for geohazards in the study region. Soil samples at two sites of study region were studied in a geotechnical laboratory. These, along with stability studies along four slope sections, have indicated the critical state of the study region. Thus, our integrated studies emphasize the crucial role of micro-gravity in finding fine subsurface structure at deeper depth level; supported by ERT and IPI at shallow depth intervals, they can satisfactorily explain the Salna sinking zone close to Lesser Himalaya. The geotechnical studies also lend support to these findings. These integrated studies have yielded a better understanding of the mass-wasting mechanism for the study region.  相似文献   

Detection of ionospheric perturbation due to a soft gamma ray repeater SGR J1550-5418 by very low frequency radio waves   总被引：1，自引：0，他引：1  

Sushanta K. Mondal  Sandip K. Chakrabarti  Sudipta Sasmal 《Astrophysics and Space Science》2012,338(2):259-264

The properties of cylindrical and spherical dust acoustic (DA) solitary and shock waves in an unmagnetized electron depleted dusty plasma consisting of inertial dust fluid and ions featuring Tsallis statistics are investigated by employing the reductive perturbation technique. A Korteweg-de Vries Burgers (KdVB) equation is derived and its numerical solution is obtained. The effects of ion nonextensivity and dust kinematic viscosity on the basic features of DA solitary and shock waves are discussed in nonplanar geometry. It is found that nonextensive nonplanar DA waves behave quite differently from their one-dimensional planar counterpart.  相似文献   

Unique Observation of a Solar Flare by Lunar Occultation During the 2010 Annular Solar Eclipse Through Ionospheric Disturbances of VLF Signals     

Surya K. Maji  Sandip K. Chakrabarti  Sushanta K. Mondal 《Earth, Moon, and Planets》2012,108(3-4):243-251

Very Low Frequency (VLF) radio waves propagate through the Earth-ionosphere waveguide. Irregularities caused by excess or deficient extreme ultra-violet and X-rays, which otherwise sustain the ionosphere, change the waveguide properties and hence the signals are modified. We report the results of monitoring of the NWC transmitter (19.8?kHz) by a receiver placed at Khukurdaha (22°27′N, 87°45′E) during the partial solar eclipse (75?%) of 15th January, 2010. The propagation path from the transmitter to the receiver crosses the annular eclipse belt. We got a clear depression in the data during the period of the eclipse. Most interestingly, there was also a X-ray flaring activity in the sun on that day which reached its peak (C-type) right after the time when the eclipse reached its maximum. We saw the effects of the occultation of this flare in our VLF signal since a part of the X-ray active region was clearly blocked by the moon. We quantitatively compared by using analogies with previous observations and found best fitting parameters for the time when the flare was occulted. We then reconstructed the VLF signal in the absence of the occulted flare. To our knowledge, this is the first such incident where the solar flare was observed through lunar occultation and that too during a partial eclipse.  相似文献